Different ways for alkaline recovery of aluminum from bauxite residue are considered from the literature and examined in experiments. The advantages and disadvantages of a hightemperature digestion via Bayer process and sodalime sintering process are elaborated and compared. As a hybrid process, bauxite residue undergoes a reductive smelting process with lime addition in an electric arc ...
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Bauxite residue, known as RM, is a solid waste produced in the Bayer process, the process of alumina extraction from bauxite ores. In the Bayer process, the sodium hydroxide solution added to a pressure vessel where bauxite ore is heated. This solution helps to dissolve the aluminum as sodium aluminate. After a series of depressurization, the ...
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Alumina Extraction Problem. In the standard Bayer Process for refining bauxite to produce alumina, the dissolution of the alumina in the ore to form sodium aluminate is accomplished in autoclaves under high pressures varying from 70 to 200 pounds per square inch. However, some lateritic bauxite ores are readily soluble in caustic, making it ...
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The Bayer process is used for refining bauxite to smelting grade alumina (Al 2 O 3 ), the precursor to aluminium. The process was developed and patented by Karl Josef Bayer 110 years ago, and has become the cornerstone of the aluminium production industry worldwide. Production of alumina reached megatonnes (Mt) worldwide by the end of 1997 ...
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Their intercalation with diasporic bauxite is complex and the removal of sulfur impurities in highsulfur bauxite is, therefore, a great challenge. Hazards of sulfur in bauxite During the dissolution process of the Bayer process, sulfur exists in bauxite in the form of 2 3SO âˆ', 2 4SO âˆ', 2S âˆ', 2 2 3S O âˆ', etc ...
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Bauxite residue is the industrial solid waste discharged from the production of alumina by bauxite, which contains a certain amount of ferric oxide in a reddishbrown color, so it is also called "red mud", and is a typical nonferrous metallurgical solid waste (Wang et al. 2018; Xue et al. 2022).The varieties of bauxite residue depend on the grade of the bauxite and alumina production process.
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The Bayer process for alumina production generates more than 160 million tons of bauxite residue annually. The current global stockpiles of bauxite residue have reached more than 4 billion tons ...
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Of all Bayer process impurities, few attract more attention than the simplest dicarboxylate. While some oxalate enters the Bayer process with bauxite as oxalic acid adsorbed on various minerals, the majority is created by the oxidation and pyrolysis of bauxite organics under Bayer digestion conditions. The rate of its formation in digestion is ...
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The Bayer process is not easily explained in brief. This method of obtaining alumina from bauxite ore is complex and involves a lengthy succession of chemical reactions, with the process varying slightly depending on the makeup of the unique source of bauxite ore. Crushed and washed bauxite ore must first go through a process to remove any ...
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The Bayer process is the most commonly used in alumina production (Liu et al. 2007), and more than 90% of alumina is produced by the Bayer process worldwide (Wang et al. 2018). Bayer red mud is an insoluble alkaline solid waste residue produced during the dissolution process of bauxite by the Bayer process (Zeng et al. 2022; Lyu et al. 2021 ...
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Bauxite is transformed into sodiumcontaminated gibbsite in the socalled Bayer process (32,33). Industrial Bayertype gibbsite can be redissolved in acids or in strongly basic solutions, and from these solutions all other aluminum compounds are produced including aluminum hydroxides and oxides (34,35) .
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The Bayer process liquor cycle is a loop, and the goal is to ensure that the energy stays within the loop, with heat exchange occurring between different parts of the cycle. The diagram shown in Fig., provided by Donaldson, simplifying the Bayer process into a large heat exchanger, highlights this idea well. Wherever possible the heat is ...
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The Bayer process for alumina production generates more than 160 million tons of bauxite residue annually. The current global stockpiles of bauxite residue have reached more than 4 billion tons with less than 2% annual recycling rate. Critical elements such as Sc and Y present an opportunity to explore bauxite residue as a secondary resource; however, low concentration affects the process ...
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Introduction. Bauxite residue, or red mud, is a solid waste produced from the alumina refining of bauxite ore. Red mud is mostly collected from the Bayer process which uses sodium hydroxide to dissolve the aluminium silicate. Typically, about 1 to tonnes of red mud remains from the production of 1 t of alumina (Zhang et al., 2011).
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Lime is an essential reagent required in various process steps of the Bayer process, in which bauxite ore is converted into alumina (Whittington et al. 1997), as illustrated in Fig. is used for improving conversion of goethite to hematite and dissolution of boehmite and diaspore during digestion; control of liquor impurities such as silica, oxalate, titanium and phosphorous; minimising ...
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In 2020, Bayer settled most of the thenpending Roundup cases for up to billion. Around 50,000 claims remain pending, according to regulatory filings. Reporting by Tom Hals in Wilmington ...
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The Bayer process. The Bayer process. Bauxite has to be processed into pure aluminium oxide (alumina) before it can be converted to aluminium by electrolysis. This is achieved through the use of the Bayer chemical process in alumina refineries. The aluminium oxide is released from the other substances in bauxite in a caustic soda solution ...
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The Bayer process is basically used for the extraction of aluminum hydrate from the bauxite ores with the mass ratio of alumina to silica (A/S) above 9. The sinter process is widely used to process the poorgrade diasporic bauxite ores with A/S below 7, in China and Russia, by sintering the bauxite ore with sodium carbonate and limestone to ...
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The digestion behavior of Australian gibbsiteboehmite bauxite and pure quartz in the Bayer process at 230250 °C was systematically studied in this paper. The mineral composition and morphology of the reaction products were characterized and the kinetics of the quartz dissolution process was studied in detail. It was shown that boehmite in ...
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Bayer process liquors are supersaturated not only with alumina but also with contaminants such as silica and oxalate which are derived from digestion of the bauxite ore with caustic liquor; such ...
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The Bayer process is a chemical process for refining aluminium hydroxide, Al(OH) 3 from bauxite; this aluminium hydroxide is subsequently calcined to produce alumina, Al 2 O 3 . The basis of the ...
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SiO 2 + 2NaOH = Na 2 SiO 3 + H 2 O. 2NaAlO 2 + 4H 2 O = 2Al (OH) 3 + 2NaOH. Bauxite with high silica content can't be purified by Bayer's process since much Al is lost due to the formation of insoluble sod, alumino silicate. Bayer's process is best adapted to bauxite containing 5560% Al 2 O 3 and relatively low (<7%) SiO 2 content.
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Aluminum production from bauxite is achieved with the Bayer process, which is a hydrometallurgical method. However, in the Bayer process, in time, it is possible to encounter problems such as the formation of excessive amounts of red mud in aluminum production, its environmental risks, its requirement of large storage sites, the excessive production of reactants by ores with low silica modulus ...
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The aim of this work was to achieve an understanding of the distribution of selected bauxite trace elements (gallium (Ga), vanadium (V), arsenic (As), chromium (Cr), rare earth elements (REEs), scandium (Sc)) in the Bayer process. The assessment was designed as a case study in an alumina plant in operation to provide an overview of the trace elements behaviour in an actual industrial setup.
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Bauxite via the Bayer process. This process will be briefly introduced in the following, as well as the reduction to aluminium, the anodes production and further steps of primary production. Alumina Production (Bayer Process) The aluminium production starts with the production of alumina from bauxite according to the socalled Bayer process.
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The Bayer process is used for refining bauxite to smelting grade alumina, the precursor to aluminum. Typically, depending upon the quality of the ore, between and tonnes of bauxite is required to produce 1 ton of alumina. The Bayer process involves the digestion of crushed bauxite in the concentrated sodium hydroxide (caustic) solution at
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Bauxite, the most important ore of aluminium, contains only 3054% alumina, Al 2 O 3, the rest being a mixture of silica, various iron oxides, and titanium alumina must be purified before it can be refined to aluminium metal. In the Bayer process, bauxite is washed with a hot solution of sodium hydroxide, NaOH, at 175°C (called digestion).
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The Bayer process is used for producing alumina (Al 2 O 3) from bauxite process was developed and patented by Karl Josef Bayer in 1887 [], which led to a dramatic reduction in the cost of aluminium process involves the following operations: mining, dissolution of the alumina at elevated temperatures, the addition of flocculants, precipitation of pure gibbsite, regeneration of ...
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Bayer process is a leaching process of bauxite. This process is use to produce high purity alumina (needed in subsequent electrolysis process) by leaching bauxite by NaOH. Leaching is done in autoclave at high presuure ( 2530 atm) and high temperature (220 o C), which produces a soluble aluminate (2NaAlO 2 ), and from which we precipitate out ...
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Introduction. Red mud (RM) is a solid byproduct generated via the caustic digestion of bauxite ores (, the Bayer process) during the production of alumina (Khairul et al., 2019), which is usually stored in large quantities in storage tanks or in the open air through dry or semidry methods (Power et al., 2011; Xue et al., 2016).Approximately 4 billion tons of RM are stored worldwide, and ...
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The bauxite ore, Bayer process materials before precipitation, mud residue, and sand residue are therefore of radiological interest, whereas the alumina product is Positional and personal monitoring data from bauxite mines and alumina refineries in Western Australia have been used to assess the abovebackground annual doses for the ...
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The Bayer Process is the most economic means of obtaining alumina from bauxite. Other processes for obtaining alumina from metal ores are also in use in some refineries, particularly in China and Russia, although these make up a relatively small percentage of global production. The process stages are: 1. Milling
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Red mud, now more frequently termed bauxite residue, is an industrial waste generated during the processing of bauxite into alumina using the Bayer process. It is composed of various oxide compounds, including the iron oxides which give its red colour. Over 95% of the alumina produced globally is through the Bayer process; for every tonne of ...
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During the digestion process of the Bayer method, lithium and gallium in bauxite will enter into the sodium aluminate solution (Tang et al. 2020; Xu et al. 2018), which will return to the digestion process for recycling after the precipitation of aluminum hydroxide from the decomposition of crystal to a large amount of red mud discharge, most of the lithium and gallium in the ...
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