Fluegas desulfurization (FGD) material is a product of a process typically used for reducing SO 2 emissions from the exhaust gas system of a coalfired boiler. The physical nature of these materials varies from a wet sludge to a dry, powdered material depending on the process.
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The desulfurization process took place at a pH of 35, the coalparticle size was 7545 μm, the pulp density was 5%, the temperature was 35°C, and the incubation time was 8 h. Chemical studies also revealed a decrease in the ash content and an increase in the calorific value of coal from 6219 cal/g to 6406 and 6315 cal/g, which indicated ...
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For future approaches, as well as desulfurization process, increasing the purity of coal may also promote the value of coal and prevent environment pollution. In the study of Etemadifar et al., growing and resting cells of heterotrophic Rhodococcus erythropolis strains PD1, R1, and FMF, and R. qingshengii were utilized in sulfur removal and ...
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The coal hydrogen production process requires hightemperature steam as a reactant. Coalfired boilers are usually used to provide hightemperature steam. The ammoniabased desulphurization process is an effective technology to remove SO2 in the coalfired flue gas. However, the mass transfer coefficient of SO2 in such an engineered process is not readily available in the literature. In this ...
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Most of the effective coal desulfurization techniques are based on chemical methods. Main desulfurization methods are chemical desulfurization, leaching, extraction, flotation, oxydesulfurization and biodesulfurization. The alkaline desulfurization is more effective in removing the pyritic sulfur from the coal, which is the less abundant form ...
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The study aims to develop a thorough understanding of the desulfurization process and establish a theoretical framework for advancing clean coal technology and efficient coal utilization. Stringent control was maintained over parameters such as particle size, pretreatment time, bacterial species, and bacterial concentration.
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In 2010, Li and coworkers demonstrated an extremely rapid, convenient and mild coal desulfurization new process using sodium borohydride and 3141% reduction of total sulphur was achieved (Li et ...
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The complicated mass transfer during coke making process leads to the uneven spatial distribution of sulfur forms in coke, which is of great importance for the sulfur transformation and desulfurization efficiency. ... Char yield and desulfurization rate of YJH coal during pyrolysis. Fig. 5 presents the release rate of H 2 S, SO 2, ...
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Abstract To explore the feasibility of organic sulfur removal using organic acids, oxalic acid, citric acid and ascorbic acid were selected as desulfurization reagents. Combined with microwave irradiation technology, desulfurization experiments of highsulfur coal treated with nitric acid were conducted. The orthogonal experimental results showed that the microwave synergistic citric acid ...
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To solve the safety problem of spontaneous combustion of highsulfur coal, applied microbiology, physical chemistry, reaction kinetics theory, combined with the SEM, FTIR and TGDTGDSC experiments and analysis of testing methods, the microbial desulfurization experiments were carried out, and the change law of the desulfurization reaction of coal before and after the element composition, main ...
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The process of sulfur removal by microbes is carried out by enzymes and is considerably influenced by different factors, including pH, temperature, nutrient composition, shaking or standing condition, coal types, and most importantly type of microorganisms used.
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Flotation desulfurization is the process of separating sulfur from coal samples into tailing products based on the differences in the physical and chemical properties of the mineral surfaces without changing the original sulfur content of the entire coal. ... and {111} facets in alk. soln., which is beneficial to the coal desulfurization. These ...
WhatsApp: +86 18203695377![Process for coal desulfurization. [use of microwave energy]](/r4m1z83/37.jpg)
A process for coal desulfurization generates extremely low amounts of heat from microwave energy to induce thermochemical, insitu, reactions to liberate sulfur in the form of stable gaseous species, such as H/sub 2/S, COS and SO/sub 2/. Inventors:
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In addition, the sulfur content of the raw coal reduces from % to %, total desulfurization rate of %, whose organic sulfur desulfurization is % after coal in shake flask experiments. And the desulfurization rate approaches the maximum value on the tenth day (from Figure 2B). It was demonstrated that strain SX12 could ...
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article{osti_, title = {Coal desulfurization by a microwave process}, author = {Zavitsanos, P D and Golden, J A and Bleiler, K W and Jacobs, I S}, abstractNote = {A laboratory size flow reactor was developed and tested on coal samples up to 100 g/batch. A modified version of the applicator will increase sample size to 1000 g; when run continuously it can handle 500 g to 1000 g/minute.
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environment, the desulfurization and denitration of flue gas in the combustion process of coal has become an important step. T his work summarizes the desulfur ization and denitration
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Abstract. Most coal requires some preparation before use. Preparation may range from simply crushing to provide a size consist suitable for certain types of boilers to extensive size reduction and cleaning to remove sulfur and ashforming mineral matter. At present, coal cleaning is accomplished through physical separation of particles low in ...
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Most of the coal, oil and natural gas produced in the world are used as fuels and a small part is used as a chemical feedstock. Undesulfurized coal and oil in the combustion process will produce a large number of sulfur oxides (SOx), serious harm to human health, and environmental damage. The unpurified natural gas containing hydrogen sulfide (H2S) is difficult for industrial application. This ...
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During the desulfurization process of coalfired power plants, there are many related parameters that affect the desulfurization efficiency. So it is very difficult to measure the desulfurization efficiency directly. In this paper, in order to reflect the relationship between monitoring process parameters and desulfurization efficiency better, a novel prediction model of desulfurization ...
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The major coal desulphurization technologies prior to combustion are physical coal cleaning, chemical and biological methods. Each has some technical and economical limitations. Physical coal cleaning can only remove limited amount of inorganic sulphur due to insufficient liberation.
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Coal desulfurization by microwave with additives has been investigated in many aspects, including desulfurization effects [38], coal property changes [39], sulfur species and dielectric characteristics [27,40]. ... XANES was used to analyze the change of sulfur forms in the desulfurization process of high organic sulfur coal under microwave ...
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Flue gas desulfurization (FGD) systems using lime or limestone as the chemical reagent are widely used throughout the world for SO 2 emissions control at coalfired power plants. Ammoniabased ...
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The flue gas desulfurization solids in the dry process (DFGDS) are the newly formed CaSO 4 and the unreacted excess of CaO. They are carried along with the coal FA out of the boiler, forming the end product (FA + DFGDS), which is highly alkaline due to the excess of CaO with respect to the initial SO 2 (Ca:S = ). Due to a low ...
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Physical desulfurization methods can only remove inorganic sulfur and are economical and practical in nature. 14,15 Highgradient magnetic separation technology is an effective method for physical desulfurization, which can be used to deal with fine particles of paramagnetic minerals and is applied to the desulfurization of fine coal (mainly ...
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The limestone gypsumbased wet desulfurization (WFGD) process is widely applied for flue gas desulfurization in coalfired power plants. However, enrichment of elemental chlorine in the desulfurization slurry would significantly impact the desulfurization efficiency, which requires regular discharge of desulfurization wastewater (He and Qi 2010).
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The FGD products are included in coal combustion products. The components of CCP's are as follows: fly ash, 57 percent; FGD products, 24 percent; bottom ash, 16 percent; and boiler slag, 3 percent. What is flue gas desulfurization? Flue gas desulfurization is a chemical process to remove sulfur oxides from the flue gas at coalburning powerplants.
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That shows desulfurization reaction in the furnace is complete. At the same time, the composition of fly ash and circulating ash are similar to each other. Before the renovation, desulfurizer is only active calcium in the raw coal during desulfurization process.
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Coal desulfurization is imperative to create clean coal and reducing harmful emissions during the combustion process. However, organic sulfur in coal is more difficult to remove than inorganic sulfur. Therefore, in this paper, a method of coal sample desulfurization using citric acid with microwave assisted was proposed, and experimental ...
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The main factor for the results above was that the desulfurization mechanisms were different. Therefore, the research of different desulfurization mechanisms is the main direction of future work. The consequence of this paper would provide data support for the selection of the desulfurization method for high sulfur coal.
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This study investigated the characteristics of mercury emitted from a largescale coalfired power plant in Taiwan via intensive sampling campaigns. The air pollution control devices equipped in this coalfired power plant include selective catalytic reduction, fabric filter and seawater flue gas desulfurization. During three sampling campaigns, mercury concentrations emitted from this large ...
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XANES was used to analyze the change of sulfur forms in the desulfurization process of high organic sulfur coal under microwave heating and conventional heating conditions. The effects of microwave fields on the molecular properties, bond strength and reaction kinetic of organic sulfurcontaining groups were studied by quantum chemical calculation.
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Coal desulfurization Full Record Related Research Abstract The Meyers process of removing pyritic sulfur from coal chemically before it is burned is presented.
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At present, the desulfurization technology is divided into pretreatment, inuse treatment, and posttreatment. Inuse treatment, in the case of coal, is generally defined as the spraying of desulfurizer into the coalburning boiler, which is capable of converting SO 2 and SO 3 emissions from coal combustion into sulfites or sulfates (Lu et al. 1998; Sun et al. 2018).
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Since the "Eleventh FiveYear Plan" period, the construction of flue gas desulfurization and denitrification facilities for coalfired power plants have been accelerated to control the emissions of sulfur dioxide (SO 2) and nitrogen oxides (NO X) and thus to address the issue of acid rain in to the goal of the "Thirteenth FiveYear Plan for Energy Saving and Emission ...
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