Bauxite residue, known as red mud, is a byproduct of alumina production using the Bayer process. Currently, its total global storage amounts to over billion tons, including about 600 million tons in Russia. The total global storage of red mud occupies large areas, leading to environmental damage and increasing environmental risks. Moreover, it contains a significant amount of sodium ...
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Hall's process for leaching of alumina from bauxite: (1) Bauxite ore and sodium carbonate are fused toghether to convert aluminium oxide into soluble sodium metaaluminate. The insoluble residue contains the impurities of silica and iron oxide. The fused mass is treated with water.
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DOI: /materproc Corpus ID: ; The Efficient Use of Sulfuric Acid in Bauxite Residue Leaching article{Toli2023TheEU, title={The Efficient Use of Sulfuric Acid in Bauxite Residue Leaching}, author={Aikaterini Toli and Dimis Kotsanis and Maria Psoma and Danai Marinos and Panagiotis Davris and Efthymios Balomenos and Dimis Panias}, journal={RawMat 2023}, year ...
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In this paper, a novel fivestep leachingbased process was developed for clean production of activatedalumina from secondary aluminum dross. Different parameters affecting alumina extraction efficiency including acid concentration, leaching time, leaching temperature, liquidtosolid ratio, and particle size were optimized.
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Introduction. Alumina (Al 2 O 3) is a material which has been studied extensively due to its wideranging applications in areas such as adsorbents and is traditionally obtained from the Bayer Process, which recovers aluminium from bauxite via a caustic digestion process, followed by crystallisation of aluminium hydroxides from the sodium aluminate mother liquor (Power et al ...
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An acidic aqueous solution of the corresponding aluminum salts was obtained by purification. These aluminum salts were then precipitated from the solution through adjusting the pH [106]. The principle processflow diagram of bauxite leaching with HCl is shown in Fig. 10.
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1. Introduction. Aluminum (Al) is the second most widely used metal globally and is primarily produced from bauxite ore. Despite the high recycling rate of scrap Al, >60% is produced from bauxite through the Bayer and HallHéroult process [27].The worldwide primary production of Al metal during 2021 was approx. million tons, with million tons alone from China [16].
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produce highly purified and fine alumina, some alternative on leaching and precipitation processes were studied. These due to leaching process tends to predetermine the rate of recovery and the purity of alumina whereas a very effective precipitation process can be applied to produce fine size of alumina powder.
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The obtained leaching residues were characterized through Xray diffraction, scanning electron microscopy and energydispersive spectrometer. ... Alumina mainly extracted from bauxite is widely used in catalysts, adsorbents, ceramics, ... A novel process for alumina extraction from ARCG was investigated systematically. The optimum conditions ...
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In the industrial production of alumina, there are three main production methods: the Bayer process, sintering process, and combined process (Liu et al. 2014a).The Bayer process is the most commonly used in alumina production (Liu et al. 2007), and more than 90% of alumina is produced by the Bayer process worldwide (Wang et al. 2018).Bayer red mud is an insoluble alkaline solid waste residue ...
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During the digestion process of the Bayer method, lithium and gallium in bauxite will enter into the sodium aluminate solution (Tang et al. 2020; Xu et al. 2018 ), which will return to the digestion process for recycling after the precipitation of aluminum hydroxide from the decomposition of crystal species.
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In terms of price, scandium is the most valuable rareearth element in bauxite residue. This research discusses the effectiveness of scandium extraction from the bauxite residue through pressure leaching in sulfuric acid solution. The method was selected to obtain high scandium recovery and leaching selectivity to iron and aluminium.
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1. Introduction. Red mud (RM) is a solid waste generated by alkali (NaOH) leaching of bauxite by the Bayer process for alumina production [].More than one ton of RM is produced for one ton of alumina (Al 2 O 3), and over 150 Mt of RM is annually stored in landfills and sea [].The RM utilization degree is extremely low due to the high Na, Al, Si, and Ca content because these elements increase ...
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The Bayer Process involved the pressure leaching of bauxite with NaOH solution to obtain sodium aluminate solution from which aluminum hydroxide was precipitated by seeding. View Show abstract
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The alumina in leaching residue with A/S> 10 can be extracted by the Bayer process if more than 90% of silica in HACG will be removed. Therefore, a novel technology of hematite (Fe 2 O 3) involved roastingalkaline leachingBayer digestion process is proposed to extract the silica and alumina in HACG [10, 11]. Kaolinite, the main min
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Lowgrade bauxite ores are not favorable in the conventional Bayer process for alumina production, as they are producing more bauxite residue (red mud) and accompanying lower alumina yield than highgrade ores. In the current study, the thermodynamics and characterization of calciumaluminate slags and pig iron produced from smelting reduction of high iron and silicacontaining bauxites are ...
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Keywords Scandium ·Rare earth elements ·Bauxite ·Bayer process Introduction The Bayer process is the main process applied to obtain alumina from bauxite ore. The mineral is dissolved using sodium hydroxide in digesters, which obtain sodium aluminate in solution and a solid phase called red mud; the two are separated by the clarification ...
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In this process the ground bauxite is leached with caustic soda (NaOH) to produce soluble sodium aluminate (NaAlO2), leaving the impurities in the insoluble residue. The aluminate solution is then decomposed producing Al (OH)3 which is calcined to produce Al2O3. Alumina Extraction Problem
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Alumina is the common name given to aluminum oxide (Al2O3). Alumina is produced from bauxite, an ore that is mined from topsoil in various tropical and subtropical regions. The Bayer process, discovered in 1887, is the primary process by which alumina is extracted from bauxite.
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The Bayer process is the main process applied to obtain alumina from bauxite ore. The mineral is dissolved using sodium hydroxide in digesters, which obtain sodium aluminate in solution and a solid phase called red mud; the two are separated by the clarification process [ 1, 2 ].
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As a hybrid process, bauxite residue undergoes a reductive smelting process with lime addition in an electric arc furnace in order to generate aluminaenriched slag. This slag is subsequently treated with highpressure caustic leaching at moderated (200300 g/l) and high (572762 g/l) sodium hydroxide concentrations.
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Nowadays, the Bayer process is the predominant method of alumina production in the world. This method is based on the leaching of precrushed bauxite in alkaline solutions. After leaching, aluminum hydroxide separates from the aluminate solution and is then calcinated to produce alumina.
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The HallHeroult process is widely used in the extraction of aluminium. In HallHeroults process, pure Al 2 O 3 is mixed with CaF 2 or Na 3 AlF 6. This results in lowering the melting point of the mixture and increases its ability to conduct electricity. A steel vessel with a lining of carbon and graphite rods is used.
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In this paper, a novel process is proposed to extract Al 2 O 3 and SiO 2 from highsilica bauxite without residue discharge, that is, sintering bauxite with Na 2 CO 3 followed by twostep leaching with water and sulfuric acid. The effects of the sintering parameters on the process were investigated, and the phase transformations during ...
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On refining bauxite by Bayers method, pure aluminium oxide is obtained which is also called alumina. In this method, bauxite powder is taken and concentrated (4 5 %) and sodium hydroxide solution is added and then heated in a closed vessel at 4 3 3 K temperature and 5 to 6 bars of pressure, for 6 to 8 hours, so that aluminium oxide present in ...
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Red mud, also referred to as bauxite residue, is the largest process waste produced during alumina production from bauxite ore by the Bayer method. Approximately 12 tons of red mud are produced for every ton of alumina produced 1. Global red mud manufacturing is anticipated to be 200 million tons annually.
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In the leaching of Alumina from bauxite, concentration of the ore is done by digesting the powdered ore with N aOH and then it is later reacted with CO2 gas. Consider the major impurities presents related to them. I. SiO2 is leached out along with Al2O3 as silicate and aluminate on reaction with N aOH. II.
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bauxite and the red mud obtained by the alkali fusionwater leach ing method from this bauxite (RMF) and the mechanism of the process were presented in our previous article [36].
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The specific process included pressure leaching by hydrochloric acidextraction separation of leaching solutiondirect pyrolysis of aluminum chloride solution to produce alumina. As shown in Fig. 1, first, the highiron bauxite was treated by acid leaching, and the solution containing aluminum chloride and ferric chloride was obtained.
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There are three primary methods for recovering alumina from aluminum ore such as Bayer process, sintered Bayer process and Pedersen process (Safarian and Kolbeinsen, 2016 ). The summary of these processes are listed in Table 1.
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Concentration of Rare Earth Elements (Sc, Y, La, Ce, Nd, Sm) in Bauxite Residue (Red Mud) Obtained by Water and Alkali Leaching of Bauxite Sintering Dust May 2020 Minerals 10(6):500
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The alumina content of a typical Kaolin is 1525% varying from place to place. Kaolin is highly silicious having around 50% silica. That is the reason it follows a different route of roasting and chloride leaching to extract alumina. Leaching with acids like HCl and H 2 SO 4 [3, 4] is
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A process of dissolution Severoonezhsk deposit boehmitekaolinite bauxite by hydrochloric acid, as well as the processes that occur during openair calcination, were investigated. A dehydration...
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Aluminum Precipitation and Alumina Preparation. NH 4 HCO 3 solution (2 mol/L) was added to the leaching solution to adjust the appropriate pH value to precipitate aluminum in the form of Al(OH) precipitation conditions were carried out in the process of precipitation with the pH range of 59, precipitation temperature range of 30°C80°C, and precipitation time range of 30 min ...
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