Coal tar ( ) and coal tar pitch ( ) are the byproducts of the hightemperature treatment of coal to make coke or natural gas. These chemical products usually are thick, black or dark brown liquids or semisolids with a naphthalenelike odor. Coal tar also has a sharp, burning taste.
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The organic chemistry industry is based on organic compounds derived from coal, petroleum and gas. Coal tars derived from the carbonisation process are complex mixtures, of which the polycyclic aromatic hydrocarbons (PAH's) are the main component. One of the most important PAH's is naphthalene, which represents between 10 to 12% of the recent years, new applications for industrial ...
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This report proffers the detailed cost evaluation of the production of naphthalene from coal tar. In this process, the coal tar is subjected to the distillation and fractionation process. Further, the middle fractions, which contain most of the naphthalene, are cooled and crystalized to yield crude naphthalene. Lastly, the crude naphthalene is ...
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The tar production rate is kg/s and is analyzed to contain 85% carbon and 15% hydrogen by weight. The heating value of the tar is 42,000 kJ/kg. The oxygen is produced from air using an oxygenseparation unit that consumes 4000 kJ of energy/kg of the oxygen produced (assume full conversion of char).
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Naphthalene has a distinctive, strong odor, which is often described as sweet or tarlike. Its melting point is around 80°C (176°F), and it boils at around 218°C (424°F). Synthesis and Production. Naphthalene is predominantly produced from coal tar, a byproduct of the coal gasification process.
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1. Introduction. With the development of coal utilization technologies such as gasification, liquefaction, carbonization, and coking, a large number of coal tar or coal tar byproducts have been produced, among which carbonization and liquefaction are the processes with coal tar as the main product. 1,2 Although medium and lowtemperature coal tars have higher contents of aliphatic ...
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Report No. COAL TAR CHEMICALS JAMES J. L. MA December 1976 A private report by the a PROCESS ECONOMICS PROGRAM STANFORD RESEARCH INSTITUTE MENLO PARK, CALIFORNIA
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Chemical Abstracts Service Registry Number: CAS (Coal tar creosote); CAS (Wood creosote). Synonyms: Coal tar oil; Brick oil; Heavy oil; Naphthalene oil; Liquid pitch; Wood creosote. Chemical/Pharmaceutical/Other Class: Phenolic Compound. Chemical Formula: A distillate of coal that contains an estimated 162 different compounds.. Estimated makeup is as follows: aliphatic ...
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% of the naphthalene in the coal tar; % of the naphthalene fraction is lost with the press runoff. 3. The market is limited because of the minimum product range: only liquid naphthalene can be shipped to the customer. (In April 2012, Rostekhnadzor banned the shipment of pressed naphthalene in railroad cars for lack of mechanization.
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But because that its relative density is higher than and asphaltene content is close to 50% [6] (mass fraction), hightemperature coal tar is not suitable for the production of aerospace fuel. Medium and low temperature coal tar is a liquid product with high condensation degree obtained by pyrolysis of lowrank coal at 600 to 800°C.
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Abstract In this study, the steam reforming of naphthalene and pyrene as heavy tar model compounds was investigated experimentally in a horizontal tube reactor and theoretically using the CHEMKIN simulation. The experimental results revealed that the reactivity of naphthalene was higher than that of pyrene in the presence of steam. The carbon content converted to soot is a little more than ...
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In the oxidation process, coal tar naphthalene and/or oxylene is vaporized, mixed with air and fed to the reactors. ... SUMMARY OF NAPHTHALENE EMISSIONS FROM ALL SOURCES Emission Source Coke byproduct recovery Naphthalene production Coal tar Petroleum Naphthalene end uses Inadvertent sources* Total All Sources Source Process 6. ...
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100 samples of recycle solvent were obtained by continuous operation (50 days) of 1 ton/day coal liquefaction plant at Kimitu. Naphthalene derivatives in the recycle solvents were anslyzed in ...
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naphthalene oil. NPCs. normalphase columns. OBSG. octyl bonded silica gel. OCAs. ... while the latter is a byproduct from coal coking process [1]. The output of coal tar accounts for 35% of coals in the furnace [2]. ... Li YC, Xin WL, Huang MG, et al. Industrial production technology of coal series needle coke. CN A, ...
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Naphthalene was first isolated from coal tar in 1819 by Alexander Garden; it represents about 10% of this complex mixture of aromatics. The industrial importance of naphthalene dates from the latter half of the last century, owing mainly to the ease with which it can be converted into sulfonic acids and thence also to the naphthols, for use as dyestuffs intermediates.
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It processes the naphthalene fraction from the rectification of coal tar so as to produce naphthalene of grade A and type II according to Technical Specifications TU 14797. Until November 2020, the naphthalene was produced at MMK by solidification of the naphthalene fraction and subsequent mechanical separation of the naphthalene crystals ...
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The company derives naphthalene from coal tar at production plants in North America, Europe, Australia, and China. NIPPON STEEL SUMITOMO METAL CORPORATION.
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Naphthalene is the most simple, commonly found, and most watersoluble PAHs in the environment. It is produced from coal tar fraction by crystallization and distillation. It is often used as dispersants in natural and synthetic rubbers, in the production of naphthalene sulfonate superplasticizers for concrete, in paints, tanning agents in the leather industry, in the production of the ...
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The invention discloses a method for extracting industrial naphthalene from coal tar, and belongs to the field of coal chemical industry. According to the method, coal tar is taken as a raw material; naphthalene is fractionated through a weightremoving column; firstly crude naphthalene is obtained; and then industrial naphthalene is prepared through a crude naphthalene rectifying column.
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Coal tar naphthalene oil fraction (CTNOF) is typically obtained as a byproduct of the coking process in steel production. When coal is subjected to high temperatures in the absence of air (coking), it undergoes thermal decomposition, yielding various byproducts including coal tar [].This tar can be further processed to extract different fractions, one of which is naphthalene oil [2, 3].
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These advantages of the hydrorefining process have attracted the attention of numerous investigators. A laboratory study has been made of the effects of temperature, partial hydrogen pressure, and space velocity on the amounts of thionapthen and tetralin in the hydroraffinate made by the catalytic hydrorefining of coaltar naphthalene.
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This research presents the first demonstration of substantial microbial degradation and depletion of naphthalene from coal tar, a multicomponent, aromatic, dense nonaqueous phase liquid (NAPL). The rates and extents of microbial degradation of naphthalene from coal tar and from a twocomponent NAPL simpler in composition than coal tar were evaluated in gently mixed, NAPL−water batch systems ...
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