Bauxite is the major alumina (Al 2 O 3 ) bearing ore used in the aluminum manufacturing industries. The bauxite containing less than 50% Al 2 O 3 is called lowgrade bauxite ore which is commonly used for the alumina based abrasives and refractories productions. The alumina silica and alumina ferrite complexes are the foremost impurities ...
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The most common process for the extraction and purification of alumina is the 'Bayer' process. The first step in the process is the mixing of ground bauxite into a solution of sodium hydroxide. By applying steam and pressure in tanks containing the mixture, the bauxite slowly dissolves. The alumina released reacts with the sodium hydroxide ...
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To produce high purity alumina as the raw material for sapphire growth, gibbsite, which is the precursor for the synthesis of alumina, was synthesized by the Bayer process, and treated with an acid solution to remove the sodium component.
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Introduction Bauxite Ores The Bayer Process Process Flowsheet and Raw Materials including Liquor Properties Ore Preparation and Grinding Desilication Digestion SolidLiquid Separation Filtration Heat Interchange Precipitation and Equilibrium Considerations Calcination Alumina Product Quality Scale Mud Washing
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A hot caustic soda (NaOH) solution is used to dissolve the aluminiumbearing minerals in the bauxite (gibbsite, böhmite and diaspore) to form a sodium aluminate supersaturated solution or "pregnant liquor". Gibbsite: Al (OH) 3 + Na + + OH → Al (OH) 4 + Na + Böhmite and Diaspore: AlO (OH) + Na + + OH + H 2 O → Al (OH) 4 + Na +
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To prevent this, a desilication process to reduce the amount of silicon in solution is conducted prior to precipitating hydrated alumina. In the Bayer process, bauxite ores are pressure leached at a high temperature (100250 °C) using sodium hydroxide solution. The leachate solution is then cooled and seeded to precipitate alumina hydrates.
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The Bayer Process, developed by Carl Josef Bayer. is the principal industrial means of refining bauxite to produce alumina (aluminium oxide). In this process, aluminium ore is treated with concentrated sodium hydroxide to form a soluble sodium aluminate. Sodium aluminate is filtered, and the filtrate on heating with water gives aluminium hydroxide.
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The ore is first converted into pure aluminium oxide by the Bayer Process, and this is then electrolysed in solution in molten cryolite another aluminium compound. The aluminium oxide has too high a melting point to electrolyse on its own. Aluminium ore. The usual aluminium ore is bauxite. Bauxite is essentially an impure aluminium oxide.
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Aluminum Geology, Historical and Industrial Perspectives. Bound tightly by oxygen and silicon, aluminum oxides and silicates, commonly referred to as alumina and/or aluminosilicate, exist naturally in ores generically termed consists mainly of the hydrated aluminum oxide (Al 2 O 3 xH 2 O) minerals gibbsite, boehmite, and diaspore, and is the world's main source of raw ...
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The Bayer Process was invented and patented in 1887 by Austrian scientist Karl Josef Bayer. Two to three tonnes of bauxite are required to produce one tonne of alumina. 90% of the global alumina supply of around 90 million tonnes is used in aluminium production. Alumina refineries tend to be located close to bauxite mines and/or ports for ...
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The Bayer process is an industrial process by which bauxite is purified into alumina, or aluminum oxide. Named for Karl Bayer, who developed it in the late 19 th century, this process is an essential intermediate step in the production of aluminum metal. Alumina is produced through a series of controlled chemical reactions from bauxite, a naturally occurring aluminum ore.
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In the Bayer process of extraction of alumina from bauxite, ... In the Bayer process of extraction of alumina from bauxite, the insoluble product generated after bauxite digestion with sodium hydroxide at elevated temperature and pressure is known as 'red mud' or 'bauxite residue'. ... Separation and Purification Technology 28: 8186 ...
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During the digestion process of the Bayer method, lithium and gallium in bauxite will enter into the sodium aluminate solution (Tang et al. 2020; Xu et al. 2018), which will return to the digestion process for recycling after the precipitation of aluminum hydroxide from the decomposition of crystal to a large amount of red mud discharge, most of the lithium and gallium in the ...
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The production of aluminum from bauxite is a twostep process: refining bauxite to obtain alumina and smelting alumina to produce aluminum. Bauxite contains a number of impurities, including iron oxide, silica, and titania. If these impurities are not removed during refining, they will alloy with and contaminate the metal during the smelting ...
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The purity of alumina produced from bauxite through the Bayer process after washing and calcination is approximately %; the remainder is Na 2 O (Park et al., 2013). According to Colonetti et ...
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The HallHéroult process is the major industrial process for smelting involves dissolving aluminium oxide (alumina) (obtained most often from bauxite, aluminium's chief ore, through the Bayer process) in molten cryolite, and electrolyzing the molten salt bath, typically in a purposebuilt cell. The HallHéroult process applied at industrial scale happens at 940980 °C and ...
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The Bayer Process was patented in 1888 in Germany by the Austrian chemist, Karl Joseph Bayer [].The simple chemistry of the process is that the hydrated forms of aluminum in bauxite, readily dissolve in heated caustic (NaOH) solutions (the DIGESTION step, see Chap. 4).The advantage is that nearly all of the minerals in bauxite containing other metallic ions do not dissolve and so can be ...
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The separation of the alumina from the impurities in the bauxite ore is usually accomplished by the Bayer Process. In this process the ground bauxite is leached with caustic soda (NaOH) to produce soluble sodium aluminate (NaAlO2), leaving the impurities in the insoluble residue. The aluminate solution is then decomposed producing Al (OH)3 ...
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The influence of process parameters in the threestage purification of aluminate solution from the Bayer process and aluminum hydroxide was considered in this paper. One of the ways of purification is treating the aluminate solution in order to reduce the concentrations in the starting raw material (solution) and then treating the aluminum hydroxide at a certain temperature and time in order ...
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As the minerals are weathered they gradually breakdown into various forms of hydrated aluminum oxide, Al 2 O 3 .xH 2 O, known as bauxite. The bauxite is purified by the Bayer Process. First the ore is mixed with a hot concentrated solution of sodium hydroxide. The NaOH will dissolve the oxides of aluminum and silicon but not other impurities ...
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The Bayer process was invented 130 years ago and remains the global method of choice for converting bauxite to alumina for aluminum and industrial alumina production. In general, the three largest problems in the Bayer process are as follows: (a) The removal of silica (a problem with high silica bauxite). (b)
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